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1 article(s) from Abdelmalek, Fatiha

Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp²)–H bond arylations

Fatiha Abdelmalek,
Fazia Derridj,
Safia Djebbar,
Jean-François Soulé and
Henri Doucet

Beilstein J. Org. Chem. 2015, 11, 2012–2020, doi:10.3762/bjoc.11.218

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Figure 1: Different pathways for the synthesis of π-conjugated molecules incorporating fluorinated phenylene ...

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Scheme 1: Pd-catalyzed desulfitative direct arylations of heteroarenes using 2,3,4-trifluorobenzenesulfonyl c...

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Scheme 2: Pd-catalyzed second arylation of 1 and 2. i) PdCl(C₃H₅)(dppb) (2 mol %), KOAc (2 equiv), DMA, 150 °...

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Scheme 3: Pd-catalyzed direct regioselective arylation of 1-methyl-2-(2,3,4-trifluorophenyl)pyrrole (4). i) P...

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Scheme 4: Pd-catalyzed direct regioselective arylation of 3-(2,3,4-trifluorophenyl)thiophenes. i) PdCl(C₃H₅)(...

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Scheme 5: Pd-catalyzed desulfitative direct arylations of heteroarenes using difluorobenzenesulfonyl chloride...

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Scheme 6: Pd-catalyzed second direct regioselective arylation of difluorophenylheteroarenes 19-23. i) PdCl(C₃H...

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Scheme 7: Pd-catalyzed iterative direct arylations of heteroarenes–fluorobenzene triads and tetrad. i) PdCl₂(...

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Scheme 8: Reactivity of pentafluorobenzenesulfonyl chloride in Pd-catalyzed direct desulfitative arylation of...

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Published 28 Oct 2015

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Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp2)–H bond arylations

Efficient synthesis of π-conjugated molecules incorporating fluorinated phenylene units through palladium-catalyzed iterative C(sp²)–H bond arylations